安徽大学学报（自然科学版）2011，Vol.35Issue(5)：89-93,5.
马来酸类可聚合乳化剂的合成及其在乳液聚合中的应用
Synthesis of a maleic polymerizable emulsifier and its application in emulsion polymerization
摘要
Abstract
The polymerizable surfactant of sodium maleic monoalkyl polyoxyethylene propylsulfonate was synthesized in three steps using maleic anhydride, dodecylpolyoxyethylene ether-9 and 1,3-propane sultone as raw materials. The structure was characterized by 'H-NMR and IR. It was shown when the polymerizable emulsifier and traditional emulsifier sodium dodecyl sulfate ( SDS) were used separately in semicontinuous polymerization of methyl methacry late-butyl acrylate-acrylic, the high rate of conversion was observed in polymerizable emulsifier,meanwhile, electrolytic stability and water resistance of the synthesized emulsion were markedly improved.关键词
可聚合乳化剂/马来酸酯/乳液聚合/合成/十二烷基硫酸钠Key words
polymerizable emulsifier/ maleate/ emulsion polymerization/ synthesis/ sodium dodecyl sulfate分类
化学化工引用本文复制引用
吕俊,余强,聂王焰,周艺峰..马来酸类可聚合乳化剂的合成及其在乳液聚合中的应用[J].安徽大学学报（自然科学版）,2011,35(5):89-93,5.基金项目
安徽省高等学校省级自然科学研究基金重点资助项目(KJ2009A51) （KJ2009A51）
安徽大学“211工程”三期学术创新团队经费资助项目(02303402) （02303402）
