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利用同步辐射X射线衍射研究家蚕的纺丝过程

黄燕 张耀鹏 罗杰 邵惠丽 胡学超

原子能科学技术2011,Vol.45Issue(7):860-867,8.
原子能科学技术2011,Vol.45Issue(7):860-867,8.

利用同步辐射X射线衍射研究家蚕的纺丝过程

Study on Spinning Process of Silkworm by Using Synchrotron Radiation X-ray Diffraction

黄燕 1张耀鹏 1罗杰 1邵惠丽 1胡学超1

作者信息

  • 1. 东华大学纤维材料改性国家重点实验室,材料科学与工程学院,化学纤维研究所,上海201620
  • 折叠

摘要

Abstract

The spinning process of a fifth instar Bombyx mori silkworm was studied in situ by synchrotron radiation wide angle X-ray diffraction (SR-WAXD). Silk glands dissected out from the larvae, and degummed cocoon silk were also examined by SR-WAXD. The effects of drying and drawing on the development of ordered structure of silk fibroin in the silk gland were investigated. The results show that ordered structures related to silk I and silk II are formed in the spinning dope near the spinneret of the silkworm head. During drying process of the silk gland, dehydration results in the formation of ordered structure of silk fibroin. Its conformation transforms to anti-parallel (3-sheet which tends to construct perfect lamellar crystalline structure of silk II during drying. In addition, drawing is another important factor to induce the formation of ordered structure of silk fibroin and resultant fiber.

关键词

同步辐射/广角X射线衍射/家蚕/成纤/有序态结构

Key words

synchrotron radiation/ wide angle X-ray diffraction/ silkworm/ fiber formation/ ordered structure

分类

数理科学

引用本文复制引用

黄燕,张耀鹏,罗杰,邵惠丽,胡学超..利用同步辐射X射线衍射研究家蚕的纺丝过程[J].原子能科学技术,2011,45(7):860-867,8.

基金项目

国家自然科学基金资助项目(50803011) (50803011)

高等学校博士学科点专项科研基金资助项目(200802550001) (200802550001)

教育部留学回国人员科研启动基金资助项目 ()

上海市教育发展基金会"晨光计划"资助项目(2007CG44) (2007CG44)

上海市浦江人才计划资助项目(09PJ1400700) (09PJ1400700)

中央高校基本科研业务费专项资金资助项目 ()

原子能科学技术

OA北大核心CSCDCSTPCD

1000-6931

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