广西师范大学学报（自然科学版）2011，Vol.29Issue(3)：43-46,4.
[Ag (pba) (Et-dtc)]·p-C6H4(CH3)2配合物的合成、晶体结构及光谱性质
Synthesis,Crystal Structure and Spectroscopic Properties of [Ag (pba) (Et-dtc) ] · p-xylene
摘要
Abstract
[Ag(pba)(Et-dtc)]· p-xylene (pba = N,N-bis((diphenylphosphino)methyl)benzenamine,Et-dtc = N-ethyldithiocarbamate) has been prepared in 4 mL CH3CN/p-xylene(1:1) and structurally characterized. The crystal is of triclinic,space group P-1 with a = 1. 003 9(2) nm,b=1. 026 22(2) nm,c = 1. 931 3(4) nm;α=86. 404(3)°,β=75. 142(2)°,γ=67. 018(2)°,Z = 2. The Ag( I ) atom in the title compound is four coordinated by two P atoms of N,N-bis((diphenylphosphino)methyl)benzenamine and two S atoms of two N-ethyl dithiocarbamate,forming a tetrahedral geometry. In the crystal,the cationsare is linked by C-H…π interactions,forming chains along the a axis(φ=168. 7°,Dlin=0. 288 1 nm). The title complex is characterized by IR and fluorescence.关键词
合成/结构/光谱性质Key words
synthesis/structure/spectroscopic properties分类
化学化工引用本文复制引用
黄廷洪,王苗,马凯,杨坤国,黄瑛达,游腾丽,王修建..[Ag (pba) (Et-dtc)]·p-C6H4(CH3)2配合物的合成、晶体结构及光谱性质[J].广西师范大学学报（自然科学版）,2011,29(3):43-46,4.基金项目
国家自然科学基金资助项目(20863001) （20863001）
广西自然科学基金资助项目(2011GXNSFA018041) （2011GXNSFA018041）
广西壮族自治区研究生教育创新计划研究生科研创新项目(2009106020703M41) （2009106020703M41）
