以5-甲基间苯二甲酸为配体的Ni(Ⅱ)配合物合成及晶体结构OACSTPCD
Synthesis and crystal structure of Ni( Ⅱ ) complex based on 5-methyl isophthalate
以5-甲基间苯二甲酸为配体与吡啶、硝酸镍反应,水热合成制得配合物5-甲基间苯二甲酸吡啶镍(Ⅱ),并培养成单晶.通过元素分析和X射线单晶衍射对其结构进行了表征,该配合物晶体属单斜晶系,空间群为C2/c,晶胞参数α＝1.961 6(6)nm,b＝1.609 3(5)nm,c＝1.475 6(5)nm,β＝111.836(4)°,Z ＝8,V＝4.324 (2)nm3,Dc＝ 1.457mg/m3,F(000)＝1 968,R1 ＝0.081 7[1＞…查看全部>>
Complexes of 5 -methyl isophthalate pyridinenickel( Ⅱ ) was synthesized from the reaction of 5 -methyl isophthalate with pyridine and nickel nitrate, and it is developed into a single crystal. The compound was characterized by elemental analysis and single crystal X-ray diffraction. It was assigned to monoclinic crystal system, space groupC2/c.cell data:α = l. 961 6(6)nm,b = l. 609 3(5)nm, c = 1.475 6(5)nm, 0 = 111. 836(4)°, Z = 8, V=4.324(2)nm3, Dc =1.457mg…查看全部>>
刘娟;王亮;郑长征;文小川
西安工程大学环境与化学工程学院,陕西西安710048西安工程大学环境与化学工程学院,陕西西安710048西安工程大学环境与化学工程学院,陕西西安710048西安工程大学环境与化学工程学院,陕西西安710048
化学化工
水热合成5-甲基间苯二甲酸镍配合物晶体结构
hydrothermal synthesis 5-methyl isophthalate nickel complex crystal structure
《纺织高校基础科学学报》 2011 (3)
413-415,427,4
陕西省自然科学基金项目(2009JM2012)
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