厦门大学学报（自然科学版）2011，Vol.50Issue(z1)：5-9,5.
(H3O)3{Cu2(H2O)2(4-ptz)4[Cr(OH)6Mo6O18]}的合成与晶体结构
Synthesis and Crystal Structure of (H3O)3{Cu2(H2O)2(4-ptz)4[Cr (OH)6 Mo6O18 ]}
摘要
Abstract
A new organic-inorganic hybrid materials based on polyoxometalates with Anderson type, (H3O)3 {Cuz (HjO); (4-ptz)4 [ H? CrMo6 O24J} ,has been hydrothermal synthesized. The single crystal structure has been determined by X-ray diffraction. The crystal data are as follows:triclinic,space group P-l,a=l. 351 2(3) nm,6=l. 353 3(3) nm,c=l. 619 8(3) nm.a= 68. 64(3)°,/3= 68. 64(3)°,r=64. 75(3)°. V= 2.466(8) nm3,Z= 2,Mr =1 822. 44,Dc= 2. 454 g/cm3 ,F(000) = 1 770, [I= 2.642 mm"1. The structure has been refined to R=Q. 062 l,wR-0.167 6 by full-matrix least-squares method. The title compound is composed of water molecules and subunits {Cu2(H2O)2(4-ptz)4[H6CrMo(iO2<]}3,''~ with 2D layer structure.关键词
杂多酸/Anderson构型/水热合成/单晶结构Key words
polyoxometalatei Anderson type/hydrothermal synthesize/single crystal structure分类
生物科学引用本文复制引用
吴小园,卢灿忠..(H3O)3{Cu2(H2O)2(4-ptz)4[Cr(OH)6Mo6O18]}的合成与晶体结构[J].厦门大学学报（自然科学版）,2011,50(z1):5-9,5.基金项目
福建省自然科学基金项目(2009HZ0004-1,2009Hz0006-1,2006L2005) （2009HZ0004-1,2009Hz0006-1,2006L2005）
