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固体碱KF/CuAl-LDOs催化制备生物柴油工艺的研究

张秋云 吴祖志 王译婕 张慧 钟蕾 周开志 马培华

大豆科学2011,Vol.30Issue(5):861-864,4.
大豆科学2011,Vol.30Issue(5):861-864,4.

固体碱KF/CuAl-LDOs催化制备生物柴油工艺的研究

Synthesis of Biodiesel by KF/CuAl-LDOs Solid Base

张秋云 1吴祖志 1王译婕 1张慧 1钟蕾 1周开志 1马培华1

作者信息

  • 1. 贵州大学化学与化工学院化学系,贵州贵阳550025
  • 折叠

摘要

Abstract

Cu-Al hydrotalcite was prepared by conventional co-precipitate method,and then loaded various amounts of KF on it as catalysts. The series of catalysts were used to synthetize biodiesel by the transesterification of soybean oil with methanol. The molar ratio of Cu-Al,catalyst dosage,KF load,methanol to oil molar ratio,reaction temperature and time in the reaction process were studied. The results showed that the optimal conditions of transesterification were as follows:molar ratio of Cu-Al with 3: 1 ,the amount of catalyst with 3% ,the load of KF with 40% ,the ratio of alcohol and oil with 9:1 .reacted at 70℃ for 1 h,the biodiesel yield up to 97.4%.

关键词

固体碱/大豆/酯交换/生物柴油

Key words

Solid base/Soybean/Transesterification/Biodiesel

分类

化学化工

引用本文复制引用

张秋云,吴祖志,王译婕,张慧,钟蕾,周开志,马培华..固体碱KF/CuAl-LDOs催化制备生物柴油工艺的研究[J].大豆科学,2011,30(5):861-864,4.

基金项目

贵州大学创新实验区建设资助项目 ()

国家大学生创新性实验计划资助项目(091065728). (091065728)

大豆科学

OA北大核心CSCDCSTPCD

1000-9841

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