波谱学杂志2011,Vol.28Issue(4):551-563,13.
烯烃聚合催化剂的ESR研究进展
Recent Progresses in ESR Studies on Catalysts for Olefin Polymerization
摘要
Abstract
Many polymerization catalysts have different transition-metal centers. In situ ESR can be used to monitor these transition metal centers having one or more unpaired electrons. Thus the reaction route and mechanisms of polymerization can be investigated by in situ ESR. In this paper, recent research progresses in ESR studies on catalysts for olefin polymerization are reviewed, including common olefin polymerization catalysts based on Ti, Ni, V and Cr.关键词
电子自旋共振(ESR)/机理/催化剂/烯烃聚合Key words
electron spin resonance/ mechanism/ catalyst/ olefin polymerization分类
数理科学引用本文复制引用
朱峰,王立,俞豪杰,赵玉来..烯烃聚合催化剂的ESR研究进展[J].波谱学杂志,2011,28(4):551-563,13.基金项目
浙江省重大科技专项(优先课题)国际科技合作资助项目(2008C14089). (优先课题)