福建师范大学学报（自然科学版）2011，Vol.27Issue(6)：54-60,7.
三啮镍配合物的合成、结构及催化降冰片烯活性研究
Syntheses and Structures of Metal Nickel ( Ⅱ ) Complexes Supported by Tridentate Ligand and Studies on Catalysis for Norbornene Polymerization
摘要
Abstract
A P ^ N ~ O ligand (2-aminophenyldiphenylphosphine salicylaldiminato ligand) and corresponding late transition metal nickel ( I ) complexes were synthesized and characterized by elemental analysis, FT-IR and X-ray single crystal diffraction. The nickel complexes were used to catalyze norbornene polymerization activated with methylalumi noxane (MAO) ,and the specific catalytic activities were evaluated at different polymerization conditions. It was found that the complexes exhibit high activities for the vinyl addition poly merization of norbornene, and the polymer shows high thermal stability and none-crystalline structure.关键词
聚烯烃/三啮/水杨醛/后过渡金属/镍/降冰片烯/甲基铝氧烷Key words
polymerization/ tridentate/ salicylaldiminato ligand/ late transition metal/nickel/ PNB/ MAO分类
化学化工引用本文复制引用
柯志聪,胡丽姗,俞颖华,陈建新,余友谊,张治纯..三啮镍配合物的合成、结构及催化降冰片烯活性研究[J].福建师范大学学报（自然科学版）,2011,27(6):54-60,7.基金项目
教育部科学技术研究重点项目(208066) （208066）
福建省自然科学基金资助项目(2010J01026) （2010J01026）
福建省教育厅重点项目(JA07029) （JA07029）
结构化学国家重点实验室资助项目(20080053) （20080053）
