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分子间缔合作用对缔合聚合物溶液阻力系数与残余阻力系数的影响

舒政 汤思斯 叶仲斌 薛新生 徐豪飞 郑川江 张卓

油气地质与采收率2011,Vol.18Issue(6):63-66,4.
油气地质与采收率2011,Vol.18Issue(6):63-66,4.

分子间缔合作用对缔合聚合物溶液阻力系数与残余阻力系数的影响

舒政 1汤思斯 1叶仲斌 1薛新生 2徐豪飞 3郑川江 1张卓1

作者信息

  • 1. 西南石油大学油气藏地质及开发工程国家重点实验室,四川成都610500
  • 2. 西南石油大学化学化工学院,四川成都610500
  • 3. 中海油研究总院,北京100027
  • 折叠

摘要

Abstract

Few attentions has been paid on the effect of intermolecular association action on resistance factor ( RF) and residual resistance factor (RRF) in associating polymer solution. In this paper, p-cyclodextrin, with "internal hydrophobic, external hy-drophilic" structure, is added into associating polymer solution to study the change of RF and RRF before and after eliminating intermolecular association action. The experiment results show that adding p-cyclodextrin can reduce the viscosity of associating polymer solution by 98% or so, spatial three-dimensional network structure is changed into loose structure similar to "Bo tree" shape, so, it is proved that p-cyclodextrin can eliminate the intermolecular association action of associating polymer solution; the contribution of intermolecular association action to establish RF is 83% or so, the contribution to establish RFF is about 59% , intermolecular association is the main way to establish resistance factor and residual resistance factor in associating polymer solution; the results of the research have referential significance in investigating the absorption of polymer solution in reservoirs.

关键词

缔合聚合物/β-环糊精/分子间缔合作用/阻力系数/残余阻力系数

Key words

associating polymer/p-cyclodextrin/intermolecular association action/resistance factor/residual resistance factor

分类

能源科技

引用本文复制引用

舒政,汤思斯,叶仲斌,薛新生,徐豪飞,郑川江,张卓..分子间缔合作用对缔合聚合物溶液阻力系数与残余阻力系数的影响[J].油气地质与采收率,2011,18(6):63-66,4.

基金项目

国家十二五重大专项课题“海上稠油化学驱油技术”子课题“聚合物强制拉伸水渗速溶技术研究”(2011ZX的5024-004-04). (2011ZX的5024-004-04)

油气地质与采收率

OA北大核心CSCDCSTPCD

1009-9603

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