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分形多孔介质的孔隙特性对气体扩散的影响

陈永利 曹立勇 何威 何榕

化工学报2011,Vol.62Issue(11):3024-3029,6.
化工学报2011,Vol.62Issue(11):3024-3029,6.DOI:10.3969/j.issn.0438-1157.2011.11.007

分形多孔介质的孔隙特性对气体扩散的影响

Effects of pore characteristics of fractal porous media on gas diffusion

陈永利 1曹立勇 1何威 1何榕1

作者信息

  • 1. 清华大学热科学与动力工程教育部重点实验室,北京100084
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摘要

Abstract

Porous particles used in combustion or catalysis were made by random walk method. The fractal characteristics of the porous particles are close to that of real ones. Based on the particle model> gas diffusion was investigated in the porous particles. Diffusion control equations were established according to the kinetic theory of gases and statistical thermodynamics. The effect of pore characteristics on gas diffusion was analyzed. The relationships between the specific area, average pore diameter and porosity with the diffusion coefficient were obtained. The results indicate that the gas diffusion coefficient decreases with the increase of specific area of pores. Gas diffusion coefficient increases as a power function of average pore diameter, and the exponent that represents the sensibility decreases linearly with the increase of porosity.

关键词

分形/多孔介质/扩散/孔隙特性

Key words

fractal/porous media/diffusion/pore characteristic

分类

数理科学

引用本文复制引用

陈永利,曹立勇,何威,何榕..分形多孔介质的孔隙特性对气体扩散的影响[J].化工学报,2011,62(11):3024-3029,6.

基金项目

国家重点基础研究发展计划项目(2006CB200305) (2006CB200305)

国家自然科学基金项目(50976055). (50976055)

化工学报

OA北大核心CSCDCSTPCD

0438-1157

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