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Synthesis, Crystal Structure and Nonlinear Optical Properties of a Novel Imidazole DerivatiVeOA

Synthesis, Crystal Structure and Nonlinear Optical Properties of a Novel Imidazole DerivatiVe

英文摘要

A new compound 1-[trans-4-((N-ethylcarbazolyl) vinyl) phenyl] imidazole(C25H22N3,Mr=364.46)has been synthesized, and its crystal structure was determined by single-crystal X-ray diffraction method. The crystal is of monoclinic, space group P21/c with a= 9.298(2) A,b=8.648(2) A,c=25.394(7) A,μ=110.46(3)°,V=1912.9(8) A3,Z=4,Do=1.266g/cm3 μ= 0.075mm-1,F(000)=772, The structure was refined to R=0.0685 and wR=0.1612 for 3570 unique reflections with Rirx=0.0645. T…查看全部>>

CHENG Le-Hua;CHU Xian-Ping;WANG Min;WANG Hai- Yan;CHEN Hong

Department of Chemistry and Material Science, ChaoHu college,ChaoHu Anhui 238000Institution of Coordination Chemistry, ChaoHu eollege,ChaoHu Anhui 238000Department of Chemistry and Material Science, ChaoHu college,ChaoHu Anhui 238000Institution of Coordination Chemistry, ChaoHu eollege,ChaoHu Anhui 238000Department of Chemistry and Material Science, ChaoHu college,ChaoHu Anhui 238000

化学化工

imidazole derivativecrystal structureπ-conjugated systemphotoluminescence

imidazole derivativecrystal structureπ-conjugated systemphotoluminescence

《巢湖学院学报》 2011 (6)

88-92,5

This work was supported by a grants for the Education Committee of Anhui Province (KJ2010B126)

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