长沙理工大学学报：自然科学版2011，Vol.8Issue(4)：92-96,5.
环己酮-异丁醛树脂的合成及表征
Synthesis and characterization of cyclohexanone-isobutyraldehyde resin
摘要
Abstract
Cyclohexanone-isobutyraldehyde resin was synthesized by condensation of cyclohexanone and isobutyraldehyde with sodium methylate as catalyst.The effect of molar ratio of materials,the amount of catalyst and reaction time on hydroxyl value,kinematic viscosity and yield of cyclohexanone-isobutyraldehyde resin was studied.FT-IR and 1H-NMR were used to characterize the structure of the resin.It was found that cyclohexanone-isobutyraldehyde resin with hydroxyl value of 43.60 mg KOH/g,kinematic viscosity of 7.78 mm2/s and yield of 52.3% was prepared when the molar ratio of isobutyraldehyde and cyclohexanone was 1.3,the amount of catalyst was 6.0 wt % and reaction time was 9 h,it exhibits better solubility in apolar solvents and yellowing-resistance than cyclohexanone-formaldehyde resin.The FT-IR and 1H-NMR results showed that the α-H of cyclohexanone reacted with isobutyraldehyde.关键词
环己酮-异丁醛树脂/合成/表征Key words
cyclohexanone-isobutyraldehyde resin/synthesis/characterization分类
化学化工引用本文复制引用
曹娇,谭淑珍,周畏龙,游红利,张一甫..环己酮-异丁醛树脂的合成及表征[J].长沙理工大学学报：自然科学版,2011,8(4):92-96,5.基金项目
湖南省科技厅科技计划资助项目 （）
