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有机电化学合成简谈

王欢 陆嘉星

电化学2011,Vol.17Issue(4):366-372,7.
电化学2011,Vol.17Issue(4):366-372,7.

有机电化学合成简谈

Brief Introduction of Organic Electrochemistry

王欢 1陆嘉星1

作者信息

  • 1. 上海市绿色化学与化工过程绿色化重点实验室,华东师范大学化学系,上海200062
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摘要

Abstract

Organic electrochemistry is a very useful tool for organic synthesis,not only because of the selective introduction or removal of electrons from organic molecules,but also for its green process.In this paper,electroorganic synthesis has been introduced from the systems,research methods and technologies to the characterization.Most of organic compounds could be electrochemically oxidized or reduced.Here,taking C C compounds as an example,several kinds of electrochemical organic synthesis reactions are discussed,such as electrochemical addition,electrocatalytic dimrization,electropolymerization,etc.Electroorganic synthesis has been industrialized since 1960s.In this paper,electrosynthesis of adiponitrile was used as an example to introduce the manufacturing technique and technological improvement.Electrochemical fixation of CO2 is also introduced.At last,future outlook is also described.

关键词

有机电化学/电化学合成/绿色化学

Key words

organic electrochemistry/electrosynthesis/green chemistry

分类

化学化工

引用本文复制引用

王欢,陆嘉星..有机电化学合成简谈[J].电化学,2011,17(4):366-372,7.

基金项目

国家自然科学基金(20973066 21173085)资助 ()

电化学

OA北大核心CSCDCSTPCD

1006-3471

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