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微乳法合成Pt/C、PtIr/C催化剂及其电化学性能表征

曾亚平 隋升

电化学2011,Vol.17Issue(4):393-398,6.
电化学2011,Vol.17Issue(4):393-398,6.

微乳法合成Pt/C、PtIr/C催化剂及其电化学性能表征

Microemulsion Preparation and Electrochemical Characterization of Pt/C,PtIr/C Electrocatalysts

曾亚平 1隋升1

作者信息

  • 1. 上海交通大学燃料电池研究所,上海200240
  • 折叠

摘要

Abstract

The Pt/C electrocatalysts were prepared by three different systems and the PtIr/C electrocatalysts were prepared with four different Ir contents.The samples were characterized by X-ray diffraction(XRD),transmission electron microscope(TEM),cyclic voltammetry(CV),potentiostatic and potentiodynamic polarizations measurements.The experimental results confirmed that the electrocatalyst particles prepared by the microemulsion method were well distributed on XC-72R supports with the active particle sizes of 5~10 nm and good electrocatalysts activity.The Pt85Ir15/C electrocatalysts showed the highest overall electrochemical activity in unitized regenerative fuel cell.

关键词

载体/微乳法/负载型催化剂/燃料电池/一体式燃料电池

Key words

support/microemulsion/supported electrocatalyst/fuel cell/unitized regenerative fuel cell

分类

信息技术与安全科学

引用本文复制引用

曾亚平,隋升..微乳法合成Pt/C、PtIr/C催化剂及其电化学性能表征[J].电化学,2011,17(4):393-398,6.

基金项目

科技部863项目 ()

上海市科学技术委员会(09510701400)资助 ()

上海交通大学分析测试中心对本课题资助.上海交通大学分析测试中心对本课题资助和协助,特此致谢. ()

电化学

OA北大核心CSCDCSTPCD

1006-3471

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