电源技术2012，Vol.36Issue(1)：49-51,78,4.
一种合成锂离子电池正极材料LiNi1/3Co1/3Mn1/3O2的新方法
A novel synthesis method of cathode material LiNi1/3Co1/3Mn1/3O2 for Li-ion batteries
摘要
Abstract
The LiNi1/3CO1/3Mn1/3O2 cathode material was synthesized in air by co-precipitation-combustion process using LiNO3, Ni(CH3COO)2·4 H2O, Co(CH3COO)2·4 H2O and Mn(CH3COO)2·4 H2D as starting materials. Its composition, morphology, structure and performances were characterized by atomic absorption spectroscopy (AAS), scanning electron microscope (SEM), X-ray diffraction (XRD) and charge/discharge test instrument respectively. The experimental results indicate that the synthesized LiNil/3Col/3Mn1/302 cathode material is well-crystallized with quite moderate and homogeneous particles; it has a-NaFeO2 layered and orderly structure and excellent electrochemical performance. When it discharges between 2.5-4.35 V, its discharge specific capacity is up to 169.05 mAh/g at first cycle, and retains 152.83 mAh/g at the 50th cycle. Under deep charge state, its structure changes less.关键词
锂离子电池/正极材料/LjNi1/3Co1/3Mn1/3O2/共沉淀-燃烧法Key words
Li-ion battery/cathode material/LiNi1/3Co1/3Mn1/3O2. Co-precipitation-combustion synthesis分类
信息技术与安全科学引用本文复制引用
闫芳,叶乃清,田华,钟卓洪..一种合成锂离子电池正极材料LiNi1/3Co1/3Mn1/3O2的新方法[J].电源技术,2012,36(1):49-51,78,4.基金项目
广西自然科学基金项目(桂科自0832256) （桂科自0832256）
