发光学报2012,Vol.33Issue(2):161-165,5.DOI:10.3788/fgxb20123302.0161
Ca2Li2BiV3O12∶Eu3+荧光粉的制备和发光性能
Synthesis and Luminescent Properties of Ca2Li2BiV3O12∶ Eu3+ Phosphor
摘要
Abstract
A novel red phosphor Ca2Li2BiV3O12: Eu3+ was synthesized by solid-state method and characterized by X-ray diffraction ( XRD) and fluorescence spectrophotometer. The influence of synthesis temperature and the concentration of Eu3 + ions, on phase compositions and luminescent properties were systematically investigated. The results show that the Ca2Li2BiV3O12: Eu3+ phosphor with high purity and crystallinity can be obtained at 650 ~ 700℃. The excitation band of the phosphor prepared covers 200 ~400 nm, the emission spectra are described by the well-known 5D0→7FJ(J = 1, 2, 3, 4) emission lines of the Eu3 + ions, the sample prepared with the Eu3 + mole fraction of 14% has the highest emission intensity. This phosphor shows a strong red emission centered at 612 nm under near-UV light and may be applied for white light-emitting diodes.关键词
Ca2Li2BiV3O12∶Eu3+/红色发光材料/固相法/能量传递Key words
Ca2Li2BiV3O12:Eu3+ / red phosphor material/ solid-state method/ energy transfer分类
数理科学引用本文复制引用
邱克辉,徐磊,李峻峰,权浩,邓科文..Ca2Li2BiV3O12∶Eu3+荧光粉的制备和发光性能[J].发光学报,2012,33(2):161-165,5.基金项目
四川省科技攻关重点项目(07GG002-002) (07GG002-002)
攀枝花市产业推进科技项目(2009CY-C-4) (2009CY-C-4)