分析化学2012，Vol.40Issue(2)：243-248,6.DOI:10.3724/SP.J.1096.2012.10565
双酚A分子印迹聚合物为萃取介质搅拌饼固相萃取的制备及其萃取性能研究
Preparation of Stir Cake Sorptive Extraction Based on Bisphenol A Imprinted Polymer and Its Extraction Performance
摘要
Abstract
A new stir cake sorptive extraction (SCSE) based on molecularly imprinted polymer (MIP) with bisphenol A (BPA) as template was prepared. The effect of preparation conditions on the extraction performance of MIP-SCSE was studied. Then, a methodology combined the stir cake sorptive extraction and liquid desorption, followed by high performance liquid chromatography with diode array detection for the direct analysis of traces of bisphenol A (BPA) in water was developed. To achieve the optimum extraction performance, several main parameters, including pH value and contents of inorganic salt in the sample matrix, extraction and desorption time, were investigated. Under the optimized experimental conditions, the method showed good linearity between 1-200 μg/L for BPA. The detection limit (S/N = 3) and quantification limit (S/N= 10) of the proposed method for BPA was 0. 67 and 2. 24 μg/L, respectively. The recoveries of spiked target compound in real samples ranged from 86. 2% -112. 2%. The MIP-SCSE shows excellent longevity and can be used more than 600 h.关键词
分子印迹聚合物/搅拌饼固相萃取/双酚A/高效液相色谱Key words
Stir cake sorptive extraction (SCSE)/ Molecularly imprinted polymer/ Bisphenol A/ High performance liquid chromatography/diode array detector (HPLC/DAD)引用本文复制引用
林福华,黄晓佳,袁东星,农舒予..双酚A分子印迹聚合物为萃取介质搅拌饼固相萃取的制备及其萃取性能研究[J].分析化学,2012,40(2):243-248,6.基金项目
本文系国家自然科学基金(No,21077085)、福建省自然科学基金(No.2010J01047)和中央高校基本科研业务费(No.CXB2011037)资助 （No,21077085）
