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预先负载原料法合成ZSM-5/SAPO-5复合分子筛

张强 李春义 山红红 杨朝合

高等学校化学学报2011,Vol.32Issue(12):2721-2726,6.
高等学校化学学报2011,Vol.32Issue(12):2721-2726,6.

预先负载原料法合成ZSM-5/SAPO-5复合分子筛

ZSM-5/SAPO-5 Composite Molecular SievesSynthesized by Preloading Raw Material Method

张强 1李春义 1山红红 1杨朝合1

作者信息

  • 1. 中国石油大学(华东)重质油国家重点实验室,青岛266555
  • 折叠

摘要

Abstract

ZSM-5 (core)/SAPO-5 ( shell) binary structure composite molecular sieves were synthesized by preloading raw material method. The effect of loading conditions on the formation and character of core/shell structure zeolite was investigated. These synthesized samples were characterized by XRD, SEM, EDS and FTIR, respectively. The results indicate that the pretreated condition affects the combination of phosphorus and ZSM-5, the crystallinity and particle morphology of composite significantly. Compared to hydrothermal synthesis method, this approach is helpful to forming smaller SAPO-5 particles and growing SAPO-5 on ZSM-5 surface under suitable pretreated condition.

关键词

核壳双结构分子筛/ZSM-5分子筛/SAPO-5分子筛/负载原料法

Key words

Core-shell binary structure zeolite/ ZSM-5 molecular sieve/ SAPO-5 molecular sieves/ Loading raw material method

分类

化学化工

引用本文复制引用

张强,李春义,山红红,杨朝合..预先负载原料法合成ZSM-5/SAPO-5复合分子筛[J].高等学校化学学报,2011,32(12):2721-2726,6.

基金项目

山东省自然科学基金(批准号:ZR2009BQ018)资助. (批准号:ZR2009BQ018)

高等学校化学学报

OA北大核心CSCDCSTPCD

0251-0790

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