高等学校化学学报2012，Vol.33Issue(2)：230-235,6.DOI:10.3969/j.issn.0251-0790.2012.02.004
掺杂CuInS2纳米晶玻璃的三阶非线性光学性质
Third-order Nonlinear Optical Properties of CuInS2 Quantum Dots Doped Glass
摘要
Abstract
CuInS2 nanociystals doped sodium borosilicate glass were prepared by employing both sol-gel and atmosphere control methods. Morphology and microstructure of CuInS2 nanociystals in the glass were characterized by means of X-ray powder diffraction (XRD) and transmission electron microscope ( TEM ). Femtosecond Z-scan technique was employed to study the third-order nonlinear optical properties of the glass. The results show that CuInS2 nanocrystals in tetragonal crystal system form uniformly in the glass, and the size of the nano-crystals is about 10 nm. The results of femtosecond Z-scan technique show that the glass exhibits excellent third-order nonlinear optical properties, and the third-order nonlinear optical refractive index y, absorption coefficient β and susceptibility x(3) of the glass are determined to be 8. 57xl0-16 m2/W, 3. 74xl0-8 m/W, and 1.95x10" mVV2, respectively.关键词
CuInS2纳米晶/钠硼硅玻璃/溶胶-凝胶法/飞秒Z扫描技术Key words
CuInS2 nanocrystal/ Sodium borosilicate glass/ Sol-gel method/ Femtosecond Z-scan technique分类
化学化工引用本文复制引用
向卫东,赵海军,杨昕宇,钟家松,罗红艳,郭玉清,梁晓娟,杨欣琪..掺杂CuInS2纳米晶玻璃的三阶非线性光学性质[J].高等学校化学学报,2012,33(2):230-235,6.基金项目
国家自然科学基金(批准号:50772075,50972107,51172165)、浙江省自然科学基金(批准号:Y4100233)和浙江省科技创新团队项目(批准号:2009 RS0010)资助. （批准号:50772075,50972107,51172165）
