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复合型镁质胶凝材料的水化相及其硬化体显微结构

蒋述兴

桂林理工大学学报2011,Vol.31Issue(4):570-573,4.
桂林理工大学学报2011,Vol.31Issue(4):570-573,4.

复合型镁质胶凝材料的水化相及其硬化体显微结构

Hydration Phase and Microscopic Characteristics of Composite Magnesium Oxychloride Cement

蒋述兴1

作者信息

  • 1. 桂林理工大学有色金属及材料加工新技术教育部重点实验室;材料科学与工程学院,广西桂林541004
  • 折叠

摘要

Abstract

In X-ray powder diffraction analysis and infrared absorption spectrum analysis, when composite magnesia cementitious material made up of caustic dolomite and calcined magnesite according to suitable proportion between the caustic dolomite and the calcined magnesite and mixed with aqueous solution of MgCl2 according to the 5 mole ratio of MgO to MgCl2, the hydration phase of the hardened composite magnesium oxychloride cement is Mg3(OH)5Cl · 4H20. The strength of the hardened composite magnesium oxychloride cement will increase when the percentage of the calcined magnesite added to the caustic dolomite. Its curing 24 h bending strength reaches 9. 07 Mpa and curing 28 d compressive strength up to 183. 50 Mpa. Thus the hardened composite magnesium oxychloride cement is formed. Its microscopic characteristics possess morphology of the main large gel phase, but not needle-bar-like crystals. The needle-bar-like crystals only exist in the holes. The main large gel phase is considered to be the source of very high mechanical strength of the composite magnesium oxychloride cement.

关键词

菱苦土/苛性白云石/复合型胶凝材料/水化相/显微结构

Key words

calcined magnesite/ caustic dolomite/ composite magnesia cementitious material/ hydration phase/ microscopic characteristic

分类

化学化工

引用本文复制引用

蒋述兴..复合型镁质胶凝材料的水化相及其硬化体显微结构[J].桂林理工大学学报,2011,31(4):570-573,4.

基金项目

广西自然科学基金项目(桂科基0639061) (桂科基0639061)

桂林理工大学学报

OA北大核心CSTPCD

1674-9057

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