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月桂酰氯对电气石的表面改性及其结构表征

边静 胡应模 杨雪 王清岭 朱建华 刘洋

硅酸盐通报2011,Vol.30Issue(5):1142-1146,5.
硅酸盐通报2011,Vol.30Issue(5):1142-1146,5.

月桂酰氯对电气石的表面改性及其结构表征

Structure Characterization and Surface Modification of Tourmaline Powder with Lauroyl Chloride

边静 1胡应模 1杨雪 1王清岭 1朱建华 1刘洋1

作者信息

  • 1. 中国地质大学(北京)材料科学与工程学院,北京100083
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摘要

Abstract

The mechanism of polycarboxylate-type superplasticizers can be explained by electrostatic repulsion and steric hindrance, but the latter gains more popularity. Based on the adsorption behavior of polymer on the solid/liquid interface, the thickness of adsorption layer and adsorption conformation are taken as parameters to study the steric hindrance caused by the polycarboxylate-type superplasticizers adsorbed on the surface of the cement particles. The paper discussed the feasibility and drawbacks of the methods of X-ray photoelectron spectroscopy ( XPS), auger electron spectroscopy ( AES) , atomic force microscope ( AFM ) , photon correlation spectroscopy ( PCS), single-molecule force spectroscopy (SMFS) , hydromechanics, ellipsometry and Monte Carlo simulation in the characterization of the steric hindrance, and makes an outlook to the research prospect of polycarboxylate-type superplasticizers.

关键词

电气石/月桂酰氯/表面改性/活化指数/疏水性

Key words

polycarboxylate-type superplasticizers/ steric hindrance/ adsorption layer thickness/ adsorption conformation/characterization method

分类

通用工业技术

引用本文复制引用

边静,胡应模,杨雪,王清岭,朱建华,刘洋..月桂酰氯对电气石的表面改性及其结构表征[J].硅酸盐通报,2011,30(5):1142-1146,5.

基金项目

国家自然科学基金(No.51072187)资助项目 (No.51072187)

硅酸盐通报

OA北大核心CSCDCSTPCD

1001-1625

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