硅酸盐学报2011，Vol.39Issue(9)：1472-1476,5.
生物形态45S5玻璃陶瓷的仿生制备和结构表征
Biomimetic Preparation and Structural Characterization of Biomorphic 45S5 Glass-ceramic
摘要
Abstract
Biomorphic 45S5 glass-ceramic with the inherent porous structure of cane was prepared by combination of plant replication method and sol–gel process.X-ray diffraction（XRD）,Fourier transform infrared spectroscopy（FTIR）,and scanning electron microscopy were employed to investigate effects of heat treatment conditions and 45S5 gel content in cane template on phase,chemical composition,and morphology of samples during the conversion of cane to biomorphic 45S5 glass-ceramic.Results show that devitrification of amorphous 45S5 gel is induced by a complex phase separation process.Resultant biomorphic 45S5 glass-ceramic consists of hexagonal Na2Ca2Si3O9 as a major crystal phase,orthorhombic NaCaPO4 and CaSiO3 as secondary crystal phases,and an unknown amorphous phase.The FTIR results confirm the results from XRD analysis.Both the heat treatment temperature and 45S5 gel content in the cane plate have a decisive effect on the morphology of the products.Under the optimum processing conditions,hierarchical porous structure of cane can be converted to 45S5 glass-ceramic.关键词
45S5玻璃陶瓷/植物模板法/微结构/溶胶-凝胶法/生物医学应用Key words
45S5 glass-ceramic/plant templating/microstructure/sol-gel process/biomedical application分类
通用工业技术引用本文复制引用
钱军民,徐明辉,张伟..生物形态45S5玻璃陶瓷的仿生制备和结构表征[J].硅酸盐学报,2011,39(9):1472-1476,5.基金项目
国家自然科学基金(50603020,50773062) （50603020,50773062）
新世纪优秀人才支持计划(NCET-07-0673) （NCET-07-0673）
陕西省自然科学基金(SJ08-ZT12)资助项目 （SJ08-ZT12）
