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新型Al、Ti改性MCM-41材料对污水中Cu~(2+)的吸附研究

方璐希 刘灿明 喻鹏 阳杰 郑为民

广州化学2011,Vol.36Issue(3):37-43,7.
广州化学2011,Vol.36Issue(3):37-43,7.

新型Al、Ti改性MCM-41材料对污水中Cu~(2+)的吸附研究

Adsorption Studies of Cu(Ⅱ) Ions from Polluted Water of New Chemically Modified Material MCM-41 with Al,Ti Ions

方璐希 1刘灿明 1喻鹏 1阳杰 1郑为民1

作者信息

  • 1. 湖南农业大学理学院应用化学系,湖南长沙410128
  • 折叠

摘要

Abstract

Adsorption behavior of Cu(Ⅱ) ions from wastewater of new chemically modified material MCM-41(mobil composition of matters) was studied.Two new kinds of material(Al-Ti-MCM-41 and Ti-Al-MCM-41) have been chemically modified with Al,Ti ions.The sample of Al-Ti-MCM-41(1∶1) was characterized by nitrogen adsorption and desorption isotherms data.The adsorption of Cu2+ on the modified materials was investigated.The effects of adsorbent dosage,temperature and initial concentration on the adsorption capacity were investigated in detail.The results showed that: The pore volume of Al-Ti-MCM-41was 0.04 cm3/g,the BJH (Barret-Joyner-Halenda) average diameter was 17.02 nm.Cu2+ was adsorbed quantitatively to the Al-Ti-MCM-41,and the absorption ratio was 99.95%.The adsorption capacity and removal percentages of Cu2+ decreased with the adsorbent dosage increased but increased with the initial concentration increased.A higher temperature was in favor of adsorption.

关键词

介孔硅基材料(MCM-41)/改性/Cu2+/吸附

Key words

mobil composition of matters(MCM-41)/modified/Cu(Ⅱ)/adsorption

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引用本文复制引用

方璐希,刘灿明,喻鹏,阳杰,郑为民..新型Al、Ti改性MCM-41材料对污水中Cu~(2+)的吸附研究[J].广州化学,2011,36(3):37-43,7.

广州化学

1009-220X

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