河北科技大学学报2011，Vol.32Issue(5)：421-425,445,6.
胶束电动毛细管色谱推扫富集测定蜂蜜中残留的杀虫脒和单甲脒
Determination of ehlordimeform and semiamitraz chloride in honey by micellar electrokinetic capillary chromatography with sweeping
摘要
Abstract
A new assay of micellar electrokinetic capillary chromatography with sweeping was developed to determine chlordimeform and semiamitraz chloride in honey. The factors affecting resolution and peak height were studied. The optimum condition for separation and enrichment is determined as that the running buffer consists of 30 mmol/L borate, 20 mmol/L sodium dodecyl sulfate and 20% (V/V) methanol whose pH is adjusted to 9. 67. The sample is injected at 10 kV for 90 s, and the separation voltage is 20 kV. Under the optimum condition, the peak enrichment factors of chlordimeform and semiamitraz-chloride are 1 100 and 1 000; the linear dynamic range is 0. 03~0. 25 mg/L; the detection limits and the average recoveries of spiked sample are 0. 88 fig/kg and 91. 8%~100. 6% for chlordimeform, and 0. 62 fig/kg and 90. 5%~102. 6% for semiamitraz chloride, respectively. The assay can meet the requirements of determination of maximum residue limits regulated by a number of countries and organizations, and can be applied to determine the residues in honey.关键词
杀虫脒/单甲脒/胶束电动毛细管色谱/推扫Key words
chlordimeform/ semiamitraz chloride/MEKC/ concentration分类
化学化工引用本文复制引用
石杰,陈冠华,童明珠,吴娴,王坤..胶束电动毛细管色谱推扫富集测定蜂蜜中残留的杀虫脒和单甲脒[J].河北科技大学学报,2011,32(5):421-425,445,6.基金项目
教育部高等学校博士学科点专项科研基金资助项目(20093227110010) （20093227110010）
江苏大学科研基金资助项目(08JDG001) （08JDG001）
江苏高校优势学科建设工程资助项目 （）
