河北科技大学学报2012，Vol.33Issue(1)：6-10,13,6.
2-氨基-6-二茂铁基-4-(2,4-二氯苯基)吡啶-3-腈类化合物的微波合成和结构表征
Synthesis of 2-amino-6-ferrocenyl-4- (2,4-dichlorophenyl)pyridine-3-carbonitrile under microwave irradiation and its crystal structure
摘要
Abstract
The title compound C24 H20 Cl2 FeN2 O2 was synthesized by the reaction of 2,4-dichlorobenzaldehyde, acetylferrocene, ethyl cyanoacetate, and ammonium acetate in aqueous medium under microwave irradiation. Its crystal structure was determined by single-crystal X-ray diffraction. The crystal is of monoclinic and space group P2:/n,a = 0. 749(3) nm,b=l. 136(3) nm,r = 2. 577(3) nm,α=γ= 90°,β= 94. 021(2)°,V=2. 188(1) nm3 , Mr = 495. 17, Dc. = 1. 503 g/cm3 , Z=4,λ = 0. 071 073 nm,μ(Wo Kα)=0. 958 mm-1 ,F(000) =1 016,R = 0. 079 7, and wR = 0. 161 6.关键词
微波辐射/二茂铁取代吡啶/晶体结构Key words
microwave irradiation/ ferrocenyl-pyridine derivatives/ crystal structure分类
化学化工引用本文复制引用
贾润红,彭菊花,屠树江..2-氨基-6-二茂铁基-4-(2,4-二氯苯基)吡啶-3-腈类化合物的微波合成和结构表征[J].河北科技大学学报,2012,33(1):6-10,13,6.基金项目
国家自然科学基金资助项目(20672090) （20672090）
江苏省自然科学基金资助项目(BK2006033) （BK2006033）
