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Zn/SBA-15介孔吸附剂的制备及脱附低浓度H_2S性能

任文玲 陈绍云 张永春 李桂民

化工进展2011,Vol.30Issue(10):2304-2309,6.
化工进展2011,Vol.30Issue(10):2304-2309,6.

Zn/SBA-15介孔吸附剂的制备及脱附低浓度H_2S性能

Preparation of Zn/SBA-15 and its desulfurization property on H_2S

任文玲 1陈绍云 1张永春 1李桂民1

作者信息

  • 1. 大连理工大学化工学院,辽宁大连116012
  • 折叠

摘要

Abstract

Mesoporous materials SBA-15 modified by different transition metals,including Zn、Fe、Mn、Cu、Co and Ni,were synthesized by impregnation method respectively.The prepared materials were characterized by XRD and BET.Among these six adsorbents,Zn/SBA-15 showed the highest H2S breakthrough capacity of 29.7 mg?g-1adsorbent with 23 wt% loading of zinc.The effect of the gas flow rate,adsorption temperature,the affects of the exit of carbon dioxide and oxygen were also investigated.Zn/SBA-15 could be recycled for four times at 573 K in air environment,and its breakthrough capacity remained same.

关键词

氧化锌/介孔分子筛/SBA-15/硫化氢

Key words

zinc oxide/mesoporous materials/SBA-15/hydrogen sulfide

分类

化学化工

引用本文复制引用

任文玲,陈绍云,张永春,李桂民..Zn/SBA-15介孔吸附剂的制备及脱附低浓度H_2S性能[J].化工进展,2011,30(10):2304-2309,6.

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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