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O,O-双十二酰化-三甲基壳聚糖季铵盐/胆固醇混合单分子膜性质

詹光耀 李明春 辛梅华 关品燊

化工进展2011,Vol.30Issue(11):2486-2490,5.
化工进展2011,Vol.30Issue(11):2486-2490,5.

O,O-双十二酰化-三甲基壳聚糖季铵盐/胆固醇混合单分子膜性质

Study on mixed monolayers of O,O-dilauryl-N,N,N-trimethyl chitosan quaternary ammonium with cholesterol

詹光耀 1李明春 1辛梅华 1关品燊1

作者信息

  • 1. 华侨大学材料科学与工程学院,环境友好功能材料教育部工程中心,福建厦门361021
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摘要

Abstract

O,O-Dilauryl-N,N,N-trimethyl chitosan quaternary ammonium(DATMC)was prepared and characterized by FTIR,EA and 1H NMR.The behaviors of mixed monolayers of DATMC and cholesterol(CH)were studied.The experimental results of monolayers properties show that the collapse pressure(πc)and the limiting molecular area(Aex)of mixed monolayers decrease with the increasing of cholestrol content.The results of compatibility indicate that the mixed system is stable as the values of excess molecular area(ΔGexc)are less than zero at any πc,and the most stable state of it is observed when molar concentration of cholestol is 0.8.The experimental results show that the properity of DATMC monolayers changes with the content of cholestrol.

关键词

壳聚糖/三甲基化/酰化/胆固醇/单分子膜

Key words

chitosan/trimethylation/acylation/cholesterol/monolayers

分类

化学化工

引用本文复制引用

詹光耀,李明春,辛梅华,关品燊..O,O-双十二酰化-三甲基壳聚糖季铵盐/胆固醇混合单分子膜性质[J].化工进展,2011,30(11):2486-2490,5.

基金项目

福建省重点科技项目 ()

福建省自然科学基金 ()

科技部科技人员服务企业项目 ()

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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