化工进展2011,Vol.30Issue(11):2549-2553,5.
羧甲基化壳聚糖修饰磁性Fe_3O_4纳米粒子去除Cu(Ⅱ)离子
Removal of Cu(Ⅱ) ions by carboxymethylated-chitosan modified magnetic Fe_3O_4 nanoparticles
摘要
Abstract
A novel magnetic nano-adsorbent was prepared by covalent binding of high-deacetylated-degree carboxymethylated chitosan onto the surface of magnetic Fe3O4 nanoparticles,which were fabricated by a chemical coprecipitation method.The adsorbent was characterized by transmission electron microscopy(TEM),Fourier transform infrared spectroscopy(FT-IR),X-ray diffraction patterns(XRD),and vibrating sample magnetomete(rVSM).Moreover,the adsorption property of the magnetic nano-adsorbent for Cu(Ⅱ) ions was also investigated.The results showed that the adsorption capability was significantly affected by pH,and the adsorption capacity was the best at pH=5.The adsorption data obeyed the Langmuir equation with a maximum adsorption capacity of 71.43 mg/g and a Langmuir adsorption equilibrium constant of 0.0543 L/mg.关键词
功能化纳米粒子/壳聚糖/Cu(Ⅱ)/吸附/Langmuir模型Key words
functionalized nanoparticles/chitosan/copper(Ⅱ) ions/adsorption/Langmuir isotherm分类
化学化工引用本文复制引用
程昌敬,左芳,吴莉莉..羧甲基化壳聚糖修饰磁性Fe_3O_4纳米粒子去除Cu(Ⅱ)离子[J].化工进展,2011,30(11):2549-2553,5.基金项目
中央高校基本科研业务费专项资金 ()
西南民族大学引进人才资助 ()
西南民族大学化学一级学科硕士点建设资金项目 ()