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羧甲基化壳聚糖修饰磁性Fe_3O_4纳米粒子去除Cu(Ⅱ)离子

程昌敬 左芳 吴莉莉

化工进展2011,Vol.30Issue(11):2549-2553,5.
化工进展2011,Vol.30Issue(11):2549-2553,5.

羧甲基化壳聚糖修饰磁性Fe_3O_4纳米粒子去除Cu(Ⅱ)离子

Removal of Cu(Ⅱ) ions by carboxymethylated-chitosan modified magnetic Fe_3O_4 nanoparticles

程昌敬 1左芳 1吴莉莉1

作者信息

  • 1. 西南民族大学化学与环境保护工程学院,四川成都610041
  • 折叠

摘要

Abstract

A novel magnetic nano-adsorbent was prepared by covalent binding of high-deacetylated-degree carboxymethylated chitosan onto the surface of magnetic Fe3O4 nanoparticles,which were fabricated by a chemical coprecipitation method.The adsorbent was characterized by transmission electron microscopy(TEM),Fourier transform infrared spectroscopy(FT-IR),X-ray diffraction patterns(XRD),and vibrating sample magnetomete(rVSM).Moreover,the adsorption property of the magnetic nano-adsorbent for Cu(Ⅱ) ions was also investigated.The results showed that the adsorption capability was significantly affected by pH,and the adsorption capacity was the best at pH=5.The adsorption data obeyed the Langmuir equation with a maximum adsorption capacity of 71.43 mg/g and a Langmuir adsorption equilibrium constant of 0.0543 L/mg.

关键词

功能化纳米粒子/壳聚糖/Cu(Ⅱ)/吸附/Langmuir模型

Key words

functionalized nanoparticles/chitosan/copper(Ⅱ) ions/adsorption/Langmuir isotherm

分类

化学化工

引用本文复制引用

程昌敬,左芳,吴莉莉..羧甲基化壳聚糖修饰磁性Fe_3O_4纳米粒子去除Cu(Ⅱ)离子[J].化工进展,2011,30(11):2549-2553,5.

基金项目

中央高校基本科研业务费专项资金 ()

西南民族大学引进人才资助 ()

西南民族大学化学一级学科硕士点建设资金项目 ()

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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