化工进展2012，Vol.31Issue(2)：339-344,6.
长碳链烯烃歧化研究进展
Advances in longer-chain aliphatic olefins metathesis
郑敏 1陈胜利 1袁桂梅 1王雪莲 1桑磊 1尤菊 1张军辉1
作者信息
- 1. 中国石油大学（北京）重质油国家重点实验室,北京102249
- 折叠
摘要
Abstract
The research of C4-olefin to produce propylene was the emphasis of aliphatic olefin metathesis technology,but attentions were also paid to longer-chain aliphatic olefins metathesis reaction.The progress of the metathesis reaction of longer-chain aliphatic olefins over rhenium based catalysis,molybdenum based catalysis and tungsten based catalysis were introduced.The study of longer-chain olefin metathesis over tungsten based catalyst,including the optimal operating condition of 1-hexene self-metathesis,1-heptene self-metathesis and 1-octene self-metathesis.The effect of pretreatment on metathesis performance of tungsten based catalyst is primarily introduced.Moreover,the studies of deactivation of metathesis catalyst by oxygenate poisoning and deactivation of tungsten based catalyst by coke formation are also introduced.关键词
歧化/铼基催化剂/钼基催化剂/钨基催化剂Key words
metathesis/rhenium based catalyst/molybdenum based catalyst/tungsten based catalyst分类
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郑敏,陈胜利,袁桂梅,王雪莲,桑磊,尤菊,张军辉..长碳链烯烃歧化研究进展[J].化工进展,2012,31(2):339-344,6.
