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改性花生壳粉对钙离子的吸附特性研究

刘光全 张华 吴百春

环境工程学报2011,Vol.5Issue(12):2733-2738,6.
环境工程学报2011,Vol.5Issue(12):2733-2738,6.

改性花生壳粉对钙离子的吸附特性研究

Study on adsorption characteristics of calcium ions on modified peanut shell

刘光全 1张华 1吴百春1

作者信息

  • 1. 中国石油集团安全环保技术研究院环保技术研究所,北京100085
  • 折叠

摘要

Abstract

Modified peanut shell was used to adsorb calcium ions from water to reduce hardness. The kinetic and equilibrium characteristics of adsorption were investigated in the uptake of calcium ions, and fourier transform infra-red (FTIR) analysis was employed to characterize the adsorbent. Results showed that 85% of the uptake by the modified peanut shell occurred in 45 min, and the adsorption equilibrium was obtained within 4 h, which was well described by a pseudo-second-order kinetic model. The equilibrium adsorption was effectively described by Langmuir adsorption isotherm. Furthermore, the adsorption increased when pH increased from 2 to 12, and a significantly high adsorption was caused by strong basicity. In fixed-bed column adsorption, the break- through curve was well fitted by the Thomas model. According to the FTIR analysis, the high content of unsatu- rated structures ( C =C, C =O) and C--O groups in modified peanut shell contributed to the adsorption of calcium ions significantly.

关键词

改性花生壳粉/钙离子/吸附动力学/等温吸附/FTIR

Key words

modified peanut shell/calcium ions/kinetic model/adsorption isotherm/FTIR

分类

资源环境

引用本文复制引用

刘光全,张华,吴百春..改性花生壳粉对钙离子的吸附特性研究[J].环境工程学报,2011,5(12):2733-2738,6.

基金项目

基金项目:国家水体污染控制与治理科技重大专项 ()

环境工程学报

OA北大核心CSCDCSTPCD

1673-9108

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