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TiO_2光催化降解水中土霉素的动力学研究

黄丽萍 陈东辉 黄满红 陈亮

环境工程学报2012,Vol.6Issue(1):57-62,6.
环境工程学报2012,Vol.6Issue(1):57-62,6.

TiO_2光催化降解水中土霉素的动力学研究

Kinetics study on photocatalytic degradation of oxytetracycline(OTC) in water by nano titanium suspended system

黄丽萍 1陈东辉 2黄满红 1陈亮1

作者信息

  • 1. 东华大学环境科学与工程学院,上海201620
  • 2. 上海应用技术学院,上海200235
  • 折叠

摘要

Abstract

The occurrences of antibiotics in aquatic environments have attracted much concern from the public.The photocatalytic degradation of OTC in water by UV/TiO2 was studied in a high pressure mercury lamp.Effects of the initial concentration,different reaction condition,TiO2 dosage,solution pH,DOM and NO-3 on the degradation rates were investigated.The results showed that the removal of OTC by photocatalytic was effective.The photodegradation rate in aqueous solution followed first-order kinetics.And after 90 minutes,74% of TOC was removed.The photodegradation rate constant ranged from 0.0619 min-1 to 0.0130 min-1 in the OTC concentration from 30 mg/L to 90 mg/L.Increasing TiO2 dosage led to the photodegradation rate constant increasing initially,followed by decreasing.Reduction of the rate constant was observed when pH increasing.It can also be affected by DOM and NO-3 in aqueous solution.

关键词

土霉素/TiO2/光催化/光降解速率常数

Key words

oxytetracycline/titanium dioxide/photocatalytic/photodegradation rate constant

分类

资源环境

引用本文复制引用

黄丽萍,陈东辉,黄满红,陈亮..TiO_2光催化降解水中土霉素的动力学研究[J].环境工程学报,2012,6(1):57-62,6.

基金项目

上海市科委重点项目 ()

高等学校博士点专项科研基金 ()

中央高校基本科研业务费专项资金项目 ()

国家自然科学基金资助项目 ()

环境工程学报

OA北大核心CSCDCSTPCD

1673-9108

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