环境工程学报2012，Vol.6Issue(2)：381-384,4.
钯/铝双金属体系对3-氯酚的脱氯降解
Dechlorination degradation of 3-chlorophenol with Pd/Al bimetallic system
摘要
Abstract
The catalytic dechlorination of 3-chlorophenol（3-CP） in aqueous solution with Pd/Al bimetallic system was investigated.The Pd/Al bimetallic particles were prepared with the cementation method.The stability of dechlorination reactivity of Pd/Al was tested.The effects of the solution pH and the amount of Pd loading at Al particles on dechlorination performance were studied.The results indicated that 3-CP（0.389 mmol/L） could be rapidly dechlorinated into phenol by Pd/Al particles with 99% conversion rate during 30 min under the conditions of pH ≤ 4.0 and 1.43% Pd loading.During the repeated tests,Pd/Al particles maintained well stability for the dechlorination of 3-CP,which is related to the spontaneously formed oxide film on Al substrate.The characterizations of Pd/Al particles indicated that the tiny Pd islets were uniformly dispersed on Al particle surface and the surface area of Al particles greatly increased due to Pd loading.As a result,the high dechlorination performance was obtained in this work.关键词
钯/铝双金属/3-氯酚/脱氯/酸性溶液Key words
Pd/Al bimetal/3-chlorophenol/dechlorination/acidic solution分类
资源环境引用本文复制引用
杨波,邓述波,余刚,赵绪新,刘剑洪..钯/铝双金属体系对3-氯酚的脱氯降解[J].环境工程学报,2012,6(2):381-384,4.基金项目
国家高技术研究发展计划（863）项目 （）
北京市优秀博士学位论文指导教师科技项目 （）
环境模拟与污染控制国家重点联合实验室专项经费 （）
深圳大学科研基金资助面上项目 （）
