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海水为溶剂合成纳米粉煤灰沸石及其性能表征

于艳卿 邹晓兰 李超峰 朱校斌

海洋科学2012,Vol.36Issue(1):49-53,5.
海洋科学2012,Vol.36Issue(1):49-53,5.

海水为溶剂合成纳米粉煤灰沸石及其性能表征

Synthesis and characterization of nano-fly ash zeolites made using seawater for crystallization

于艳卿 1邹晓兰 1李超峰 1朱校斌2

作者信息

  • 1. 中国科学院海洋研究所,山东青岛266071/中国科学院研究生院,北京100049
  • 2. 中国科学院海洋研究所,山东青岛266071
  • 折叠

摘要

Abstract

Nano-fly ash zeolites were synthesized using fusion method with seawater as solvent. The synthetic conditions were as follows: ash/NaOH quality ratio is 1:1.2, fusion temperature is 550℃, the mixture/seawater volume ratio is 1:5, reaction temperature is 100℃ and reaction time is 6h. The structure, appearance and properties of the products were characterized and analyzed in detail with both instrumental and chemical analysis methods. In addi- tion, the mineral composition, crystallization, surface area, capacity of the cation exchange, average particle size and chemical composition of synthesized zeolites were investigated and compared. The results showed that the product is a mixture of NaX zeolite and hydroxysodalite. This synthesized zeolite by fusion method using seawater for crystallization has higher purity and better crystallization than that by conventional hydrothermal method. The properties and characters of this synthesized zeolite show that it has good application values.

关键词

粉煤灰/海水/熔融水热法/沸石

Key words

coal fly ash/seawater/melting hydrothermal method/zeolites

分类

资源环境

引用本文复制引用

于艳卿,邹晓兰,李超峰,朱校斌..海水为溶剂合成纳米粉煤灰沸石及其性能表征[J].海洋科学,2012,36(1):49-53,5.

基金项目

基金项目:国家十一五科技支撑计划项目 ()

国家863计划项目 ()

国家自然科学基金项目 ()

海洋科学

OA北大核心CSCDCSTPCD

1000-3096

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