3,3’-二硝基-4,4’-偶氮氧化呋咱的合成及性能OA北大核心CSCDCSTPCD
Synthesis and Properties of High Energetic Compound 3,3'-Dinitro-4,4'-azofuroxan
以丙二酸单酰肼单钾盐为原材料,经硝化和哑硝化反应“一锅法”合成了4-氨基-3-叠氮羰基氧化呋咱(AN-FO),然后通过ANFO合成出3,3 ’-二氨基-4,4’-偶氮氧化呋咱(DAAFO),DAAFO在双氧水/浓硫酸溶液中氧化为DNAFO.用元素分析、IR、MS和DSC-TG对其结构进行了表征.结果表明,丙二酸单肼单钾盐在25～30℃硝化30min,然后在-22±2℃亚硝化60min,生成3,4-二叠氮羰基氧化呋咱(AAF).AAF在80℃环氧六…查看全部>>
4-Amino-3-azidocarbonylfuroxan (ANFO) was first synthesized via nitration and nitrosation in "one-pot", using malonic acid monohydrazide monopotassium salt as starting material. Then 3, 3'-diamino-4, 4'-azofuroxan (DAAFO)was prepared using ANFO. Finally,DAAFO were directly oxidized to DNAFO by hydrogen peroxide/sul-furic acid solution. The structures of these compounds were characterized by elementary analyses, FTIR, MS and DSC-TG. The reaction condition for…查看全部>>
何金选;卢艳华;雷晴;曹一林
湖北航天化学技术研究所,湖北襄阳441003湖北航天化学技术研究所,湖北襄阳441003湖北航天化学技术研究所,湖北襄阳441003湖北航天化学技术研究所,湖北襄阳441003
军事科技
有机化学高能化合物4-氨基-3-叠氮羰基氧化呋咱3,3’-二硝基-4,4’-偶氮氧化呋咱
organic chemistry high energetic compounds 4-amino-3-azidocarbonylfurxan 3,3'-dinitro-4,4'-azofu-roxan
《火炸药学报》 2011 (5)
9-12,4
国家安全重大基础研究项目
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