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偏二甲肼苦味酸盐的合成与性能

慕晓刚 刘祥萱 王煊军 韩启龙 李霞

火炸药学报2011,Vol.34Issue(6):88-90,3.
火炸药学报2011,Vol.34Issue(6):88-90,3.

偏二甲肼苦味酸盐的合成与性能

Synthesis and Properties of Unsymmetrical Dimethylhydrazine(UDMH) Picrate

慕晓刚 1刘祥萱 1王煊军 1韩启龙 1李霞1

作者信息

  • 1. 第二炮兵工程学院,陕西西安710025
  • 折叠

摘要

Abstract

In order to solve the problem of reusing rejected unsymmetrical dimethylhydrazine(UDMH) ,a new compound named UDMH picrate was synthesized. Its molecular structure and thermal behavior were characterized by elemental analyses,FT IR,1H NMR,TG/DTG and DSC. The results showed that thermal decomposition of UDMH oxalate occurred over the temperature range from 175. 8°C to 244. 3°C and its melting point was about 152°C. The main thermal decomposition products of UDMH picrate obtained by TG-FTIR analysis were CO2 , H2O,NO2 ,N2O and NH3 etc.

关键词

有机化学/偏二甲肼苦味酸盐/合成/表征

Key words

organic chemistry/unsymmetrical dimethylhydrazine picrate/synthesis/characterization

分类

军事科技

引用本文复制引用

慕晓刚,刘祥萱,王煊军,韩启龙,李霞..偏二甲肼苦味酸盐的合成与性能[J].火炸药学报,2011,34(6):88-90,3.

火炸药学报

OA北大核心CSCDCSTPCD

1007-7812

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