江汉大学学报：自然科学版2011，Vol.39Issue(3)：49-52,4.
壬基酚基于乙炔黑/壳聚糖膜修饰电极的电化学测定
Electrochemical Determination of Nonylphenol Based on Acetylene Black/Chitosan Film Modified Electrode
摘要
Abstract
The electrochemical method for the determination of nonylphenol based on the acetylene black/ chitosan film modified electrode was developed.The electrochemical behaviors of no-nylphenol at the bare electrode and at the film electrode were investigated respectively and the experimental conditions were optimized.The experimental results indicated that the obvious electrochemical response of nonylphenol was shown at the black/chitosan film modified electrode in pH7.0 phosphate buffer solution.Compared with the bare electrode,the oxidation peak current increased greatly at the film electrode and the peak potential shifted negatively about 50 mV,which indicated that the film electrode had a good catalytic effect to the oxidation of nonylphenol.The repeatability and stability of the modified electrode were also investigated.The electrochemical behaviors of nonylphenol were investigated.The cyclic voltammetric experimental results also showed that there existed an excellent linear relationship between oxidation peak current of nonylphenol and its concentration in the range of 110～1 10 mol/L.The detection limit is up to 5 10 mol/L（based on / = 3）.The film electrode had a good stability and an anti-interference ability.It was applied to determine nonylphenol of real water samples in Sanjiao Lake with satisfactory results.关键词
壬基酚/乙炔黑/壳聚糖/化学修饰电极/循环伏安法Key words
nonylphenol/acetylene black/chitosan/chemically modified electrode/cyclic voltammetry分类
化学化工引用本文复制引用
王亚珍,张芮,李高,靳玉峰..壬基酚基于乙炔黑/壳聚糖膜修饰电极的电化学测定[J].江汉大学学报：自然科学版,2011,39(3):49-52,4.基金项目
国家自然科学基金资助项目 （）
