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高压下激光染料分子的超快能量弛豫过程

刘丙国 贺春元 杨中娟 朱红玉

河南理工大学学报:自然科学版2011,Vol.30Issue(4):497-501,5.
河南理工大学学报:自然科学版2011,Vol.30Issue(4):497-501,5.

高压下激光染料分子的超快能量弛豫过程

Ultrafast energy relaxation process of laser dye molecules at high pressure

刘丙国 1贺春元 1杨中娟 1朱红玉1

作者信息

  • 1. 河南理工大学物理化学学院,河南焦作454000
  • 折叠

摘要

Abstract

The ultrafast molecular energy relaxation dynamic processes of LDS698 molecules at high pressure were studied by using the technique combined femtosecond time-resolved spectral measurement with high pressure generation.The results indicated that the LDS698 solution solidified at about 3.0 GPa.The pressure effects on the energy relaxation of the excited molecules are different.When the pressure is lower than 3.0 GPa,the pressure effects on the intra-and inter-molecular energy relaxation are all significant;and when the pressure is higher than 3.0 GPa,the pressure effect on the intra-molecular energy relaxation can be neglected,but the effect on the intermolecular relaxation is also significant.Using the theories suggested the pressure effects on the ultrafast energy relaxation are satisfactorily interpreted.The results also indicated that pressure could influence on the molecular energy gaps,the intermolecular interaction,and the solution thermal conduction.

关键词

高压/满足染料/飞秒时间分辨光谱/超快能量弛豫

Key words

high pressure/femtosecond time-resolved spectroscopy/ultrafast energy relaxation

分类

数理科学

引用本文复制引用

刘丙国,贺春元,杨中娟,朱红玉..高压下激光染料分子的超快能量弛豫过程[J].河南理工大学学报:自然科学版,2011,30(4):497-501,5.

基金项目

国家自然科学基金资助项目 ()

河南理工大学博士基金资助项目 ()

河南理工大学学报:自然科学版

OA北大核心CSTPCD

1673-9787

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