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微藻超临界甲醇直接酯交换法制备生物柴油

张贵芝 王勇 曹宁 杜畅

生物质化学工程2012,Vol.46Issue(1):6-10,5.
生物质化学工程2012,Vol.46Issue(1):6-10,5.

微藻超临界甲醇直接酯交换法制备生物柴油

Preparation of Biodiesel from Microalgae by Direct Transesterification under Supercritical Methanol Conditions

张贵芝 1王勇 1曹宁 1杜畅1

作者信息

  • 1. 中国石油大学华东机电工程学院,山东青岛266555
  • 折叠

摘要

Abstract

In this paper,the liquid bio-fuel from Chorella in large-scale cultivation was prepared by supercritical methanol transesterification.By the analysis of composition,the basic physics and chemistry characterization,the process parameters were optimized depending on the biodiesel yield.The results showed that the yield of the liquid bio-fuel from microalgae could reach up to 9 % under the reaction condition: ratio of methanol to wet algae(ca.50 % moisture) 8 ∶ 1(mL ∶ g),reaction temperature 260 ℃,reaction pressure 9 MPa and retention time 10 min.Meanwhile,the products had similar physical and chemical properties and ingredient composition to fossil diesel.

关键词

微藻/生物柴油/超临界甲醇/酯交换

Key words

microalgae/biodiesel/supercritical methanol/transesterification

分类

化学化工

引用本文复制引用

张贵芝,王勇,曹宁,杜畅..微藻超临界甲醇直接酯交换法制备生物柴油[J].生物质化学工程,2012,46(1):6-10,5.

基金项目

中国石油大学自主创新科研计划项目 ()

中国石油大学研究生创新实践中心“金点子”项目 ()

生物质化学工程

1673-5854

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