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微电解-Fenton氧化法去除垃圾渗滤液中有机物

朱兆连 孙敏 杨峰 王海玲 徐炎华 李爱民

南京工业大学学报(自然科学版)2011,Vol.33Issue(6):20-25,6.
南京工业大学学报(自然科学版)2011,Vol.33Issue(6):20-25,6.DOI:10.3969/j.issn.1671-7627.2011.06.005

微电解-Fenton氧化法去除垃圾渗滤液中有机物

Removal of organic pollutants in landfill leachate by microelectrolysis-Fenton process

朱兆连 1孙敏 2杨峰 1王海玲 2徐炎华 2李爱民2

作者信息

  • 1. 南京工业大学环境学院,江苏南京210009
  • 2. 南京大学环境学院,污染控制与资源化研究国家重点实验室,江苏南京210093
  • 折叠

摘要

Abstract

Iron-carbon microelectrolysis and its Fenton process were used to treat landfill leachate. The factors, such as pH, reagent dosage, reagent ratio, and reaction time were investigated. The landfill leachate COD decreased to 5 960 mg/L and COD removal reached 51.8% after iron-carbon microelectrolysis under the optimal conditions of initial pH value of 3, iron to carbon mass ratio of 4, iron-carbon dosage of 0. 6 g/L, and reaction time of 60 min. The optimal operating conditions of iron-carbon microelec-trolysis-Fenton process were H2O2 dosage of 11 mL/L and the reaction time of 100 min after iron-carbon microelectrolysis. The landfill leachate COD after iron-carbon microelectrolysis-Fenton process decreased to 4 480 mg/L and COD removal reached 63. 8%. Humic matters of large molecule were removed and decomposed into small molecular compounds after iron-carbon microelectrolysis and its Fenton process. Fenton process had stronger destruction performance for humic matters than iron-carbon microelectrolysis.

关键词

垃圾渗滤液/Fe/C微电解/Fenton氧化

Key words

landfill leachate/iron-carbon microelectrolysis/Fenton oxidation

分类

资源环境

引用本文复制引用

朱兆连,孙敏,杨峰,王海玲,徐炎华,李爱民..微电解-Fenton氧化法去除垃圾渗滤液中有机物[J].南京工业大学学报(自然科学版),2011,33(6):20-25,6.

基金项目

江苏省自然科学基金资助项目(BK2010559) (BK2010559)

江苏省高校自然科学研究项目(10KJB610004,09 KJB610002) (10KJB610004,09 KJB610002)

南京工业大学学报(自然科学版)

OA北大核心CHSSCDCSTPCD

1671-7627

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