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四元聚合缓蚀阻垢剂PMAHP的制备与表征

王芳 王平 金乐娟 王小祥 王小伟 刘霖

南京林业大学学报(自然科学版)2011,Vol.35Issue(6):86-90,5.
南京林业大学学报(自然科学版)2011,Vol.35Issue(6):86-90,5.DOI:10.3969/j.issn.1000-2006.2011.06.018

四元聚合缓蚀阻垢剂PMAHP的制备与表征

Preparation and characterization of the quadripolymer scale and corrosion inhibitor PMAHP

王芳 1王平 1金乐娟 1王小祥 1王小伟 1刘霖1

作者信息

  • 1. 南京林业大学化学工程学院,江苏 南京 210037
  • 折叠

摘要

Abstract

A novel scale and corrosion inhibitor PMAHP was synthesized by aqueous quadripolynierization using maleic anhydride (MA) , acrylic acid (AA) , hydroxyethyl acrylate (HEA) , and 2-phosphonobutane-1 ,2,4-tricarboxylic acid (PBTCA) as the raw materials initiated by sodium hypophosphite/sodium persulfate, and the optimal technological conditions were determined. When 20 mg/L of this quadripolymer is used, the scale inhibition rates of CaCO3 and Ca3 ( PO4 ) 2 are 68. 2 % and 90. 0 % respectively and corrosion inhibition rate is 56. 6 % . The infrared spectrum indicates that PMAHP contains carboxyl, phosphonyl acid groups in its molecular structure.

关键词

缓蚀阻垢剂/水溶液聚合/四元共聚物/阻垢率/缓蚀率

Key words

scale and corrosion inhibitor/ water solution polymerization/ quadripolymer/ scale inhibition rate/ corrosion inhibition rate

分类

化学化工

引用本文复制引用

王芳,王平,金乐娟,王小祥,王小伟,刘霖..四元聚合缓蚀阻垢剂PMAHP的制备与表征[J].南京林业大学学报(自然科学版),2011,35(6):86-90,5.

基金项目

国家自然科学基金项目(30771696) (30771696)

江苏高校优势学科建设工程资助项目 ()

南京林业大学学报(自然科学版)

OA北大核心CSCDCSTPCD

1000-2006

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