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微波干燥对天然橡胶硫化胶热氧老化性能的影响

张福全 陈美 王永周 廖建和 黄茂芳

热带作物学报2011,Vol.32Issue(9):1760-1764,5.
热带作物学报2011,Vol.32Issue(9):1760-1764,5.DOI:10.3969/j.issn.1000-2561.2011.09.037

微波干燥对天然橡胶硫化胶热氧老化性能的影响

The Influence of Microwave Drying on Thermal-oxidation Ageing Properties of Nature Rubber Vulcanized

张福全 1陈美 2王永周 3廖建和 2黄茂芳3

作者信息

  • 1. 海南大学材料与化工学院,海南海口 570228
  • 2. 中国热带农业科学院农产品加工研究所 广东湛江524001
  • 3. 农业部热带作物加工重点开放实验室 广东湛江524001
  • 折叠

摘要

Abstract

The thermal -oxidation ageing properties of nature rubber vulcanized dried by three methods was studied. TC and DTG was used to determine the thermal-oxidation degradation temperature in air atmosphere and thermal degradation active energy in N2 atmosphere using Coats-Redfern equation; the frequency sweep was used to estimate the ageing resistance of nature rubber vulcanized at strain of 0.5, also, the mechanical properties of rubber vulcanized was tested before and after ageing. Showed from the results, the mechanical properties of NR dried by microwave was higher than the hot -air drying and nature drying; the increasing value of tanS in frequency sweep was larger than the other drying methods; the degradation active energy dried by microwave was 9 kj/mol bigger than hot-air drying, so, the thermal stability of nature rubber dried by microwave was remarkably improved compared with the other two drying methods.

关键词

微波干燥/天然橡胶/热氧老化

Key words

Microwave drying/ Nature rubber/ Thermal-oxidation ageing

分类

化学化工

引用本文复制引用

张福全,陈美,王永周,廖建和,黄茂芳..微波干燥对天然橡胶硫化胶热氧老化性能的影响[J].热带作物学报,2011,32(9):1760-1764,5.

基金项目

国家自然科学基金资助项目(No.50663003) (No.50663003)

现代农业产业技术体系建设专项资金资助项目(No.CARS-34-GW9) (No.CARS-34-GW9)

海南省自然 科学基金资助项目(No.510213). (No.510213)

热带作物学报

OA北大核心CSCDCSTPCD

1000-2561

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