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WO3薄膜的电致变色与响应时间机理研究

杨海刚 宋桂林 张基东 王天兴 常方高

人工晶体学报2011,Vol.40Issue(5):1316-1321,6.
人工晶体学报2011,Vol.40Issue(5):1316-1321,6.

WO3薄膜的电致变色与响应时间机理研究

Response Time and Electrochromic Mechanism of WO3 Films

杨海刚 1宋桂林 2张基东 1王天兴 2常方高1

作者信息

  • 1. 河南师范大学物理与信息工程学院,新乡453007
  • 2. 河南省光伏材料重点实验室,新乡453007
  • 折叠

摘要

Abstract

Nanoscaled tungsten oxide films were fabricated by reactive DC magnetron sputtering. The influence of deposition gas pressure on surface morphology and microstructure of tungsten oxides was studied. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were utilized to characterize the micro-structural of the prepared thin films. Electrochromic and response time properties were researched by simultaneous spectrophotometric and cyclic voltametric measurements of tungsten oxides. The investigation results showed that micro-porous nanostructure has strong effects on the electrochemical and chromogenic properties, which depending on the specific surface area. For deposition gas pressure being 4 Pa, the modulating range of the visible optical transmittance can reach 71. 6% , the colored response time is 5 s, and the bleached response time is 16 s.

关键词

WO3薄膜/磁控溅射/电致变色/响应时间

Key words

WO3 thin films/ magnetron sputtering/ electrochromism/ response time

分类

数理科学

引用本文复制引用

杨海刚,宋桂林,张基东,王天兴,常方高..WO3薄膜的电致变色与响应时间机理研究[J].人工晶体学报,2011,40(5):1316-1321,6.

基金项目

河南省重点科技攻关计划项目(102102210184) (102102210184)

河南省教育厅自然科学研究项目(2010B140008) (2010B140008)

人工晶体学报

OA北大核心CSCDCSTPCD

1000-985X

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