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原料对自由落下床中生物质与煤共热解行为的影响

魏立纲 张丽 徐绍平

燃料化学学报2011,Vol.39Issue(10):728-734,7.
燃料化学学报2011,Vol.39Issue(10):728-734,7.

原料对自由落下床中生物质与煤共热解行为的影响

Effects of feedstockon co-pyrolysis of biomass and coal in a free fall reactor

魏立纲 1张丽 2徐绍平1

作者信息

  • 1. 大连理工大学化工学院精细化工国家重点实验室,辽宁大连116012
  • 2. 大连工业大学轻工与化学工程学院,辽宁大连116034
  • 折叠

摘要

Abstract

Effects of feedstock on the co-pyrolysis of biomass and coal were investigated in a free fall reactor at 500°C~700°Cwith biomass blending ratio of 0 ~100%(mass ratio).The selected coal samples were Dayan brown coal (DY) and Tiefa bituminous coal(TF),and the biomass samples were agricultural residues legume straw (LS) and woody residues pine sawdust (SD).The results indicate that the synergy can occur even in a short gas residence time during the co-pyrolysis of biomass and coal in a free-fall reactor.The product yields and the CO2 reactivity of char from the co-pyrolysis are greatly influenced by the type of feedstock.The synergy in the presence of LS with high holocellulose and ash content is more significant than that in the presence of SD.The liquid yield of high rank TF co-pyrolysis is higher than that of low rank DY coal.The char reactivity can be improved by the co-pyrolysis at specific conditions.The co-pyrolysis in presence of DY can improve the reactivity of the produced char.

关键词

生物质//共热解

Key words

biomass/coal/co-pyrolysis

分类

化学化工

引用本文复制引用

魏立纲,张丽,徐绍平..原料对自由落下床中生物质与煤共热解行为的影响[J].燃料化学学报,2011,39(10):728-734,7.

基金项目

National Natural Science Foundation of China (50776013) (50776013)

National High Technology Research and Development Program (863 Program,2008AA05Z407) (863 Program,2008AA05Z407)

Program for Liaoning Excellent Talents in University (2009R10). (2009R10)

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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