四川理工学院学报：自然科学版2011，Vol.24Issue(5)：505-508,4.
氢键和π-π堆积构筑的二维超分子配合物[Cd（phen）_3]（H_2 abtc）·0.5（H_4 abtc）·CH_3OH的结构与荧光光谱
Crystal Structure and Fluorescence Spectrum of a Novel 2D Supramolecular Complex [Cd（phen）_3]（H_2 abtc）·0.5（H_4 abtc）·CH_3OH via Hydrogen Bonding and π-π Stacking Interactions
摘要
Abstract
A novel supramolecular complex [Cd（phen）3]（H2abtc）·0.5（H4abtc）·CH3OH（1）（phen=1,10-phenanthroline hydrate,H4abtc=3,3′,4,4′-azobenzenetetracarboxylic acid） has been synthesized in situ reaction of 3,3′,4,4′-azobenzenetetracarboxylic acid and 1,10-phenanthroline hydrate with a Cd（II） salt and structurally characterized by single crystal X-ray diffraction and fluorescence spectrum.In the complex,the Cd atoms take six-coordinated with six N atoms from three phen forming distorted octahedral geometry.Interestingly,the structure of the complex 1 exhibits interesting one-dimensional Z chain networks and two-dimensional networks were formed by hydrogen bonds（O-H…O and C-H…O）.关键词
3,3＇,4,4＇-偶氮苯四甲酸/晶体结构/氢键/荧光光谱Key words
3/3′/4/4′-diazenediyldiphthalic acid/crystal structure/hydrogen bonds/fluorescence spectrum分类
化学化工引用本文复制引用
路璐,王军,谢斌..氢键和π-π堆积构筑的二维超分子配合物[Cd（phen）_3]（H_2 abtc）·0.5（H_4 abtc）·CH_3OH的结构与荧光光谱[J].四川理工学院学报：自然科学版,2011,24(5):505-508,4.基金项目
四川理工学院科研基金项目（2009xjkpL003 （）
2010XJKYL005） （）
