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ZnO含量对Li2O-ZnO—SiO2玻璃析晶及性能的影响

陈立宗 吴守平 田清波

山东科学2011,Vol.24Issue(5):26-29,4.
山东科学2011,Vol.24Issue(5):26-29,4.

ZnO含量对Li2O-ZnO—SiO2玻璃析晶及性能的影响

Effects of ZnO content on the crystallization and property of Li2O-ZnO-SiO2 glass

陈立宗 1吴守平 2田清波2

作者信息

  • 1. 山东省分析测试中心,山东济南250014
  • 2. 山东建筑大学材料科学与工程学院,山东济南250101
  • 折叠

摘要

Abstract

We addressed the effects of different ZnO content on the crystallization behavior and property of the Li2O-ZnO-SiO2 glass system with differential scanning calorimeters (DSC), x-ray diffraction (XRD) and scanning electronic microscope (SEM). Experimental results show that its precipitated phases are cristobalite, tridymite, Li2SiZnO4and SiO2. The relative cristobalite content initially increases and then decreases with the increase of ZnO content The cristobalite phase influenced thermal expansion coefficient α also initially increases and then decreases. The relative cristobalite content reaches the highest value when the ZnO content arrives at 21. 1%. Its thermal expansion coefficient reaches the maximum value of 19.13 × 10^-6/℃ when the ZnO content arrives at 26.7%.

关键词

微晶玻璃/晶核剂/ZnO/Li2O-ZnO—SiO2体系

Key words

glass-ceramic/nucleating agent/ZnO/Li2O-ZnO-SiO2 glass system

分类

化学化工

引用本文复制引用

陈立宗,吴守平,田清波..ZnO含量对Li2O-ZnO—SiO2玻璃析晶及性能的影响[J].山东科学,2011,24(5):26-29,4.

基金项目

山东省中青年科学家奖励基金项目 ()

山东科学

OACSTPCD

1002-4026

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