钴(Ⅱ)镍(Ⅱ)超分子配合物的微波合成、晶体结构OACSTPCD
Microwave Synthesis and Crystal Structure of Co(Ⅱ) and Ni(Ⅱ) Supramolecular Complexes
本文采用微波加热技术合成两种新的超分子配合物[ Co(OBT) (2,6-pdc) (H2O)2] ·3H2O(1)和[Ni(OBT)(2,6-pdc)( H2O)2] ·2H2O (2)(2,6-H2pdc =2,6-吡啶二羧酸,HOBT=1-羟基苯并三唑),并由X-射线单晶衍射分析确定了它们的晶体结构.配合物1属于三斜晶系,P-1空间群,晶胞参数:a=0.67000(13) nm,b=1.008 0(2) nm,c=1.0100(2) nm,…查看全部>>
Two novel supramolecular complexes;[ Co( OBT ) ( 2;6-pdc ) ( H2 O) 2 ] ? 3 H2 O (1) and [ Ni(OBT) ( 2;6-pdc) (H2O)2] ·2H2O (2) .were synthesised and characterized by X-ray diffraction. The complex 1 crystallized in the triclinic space P-1 with 0 = 0.67000(13) nm;b = 1. 0 080(2) nm;c = 1. 0 100(2) nm;α = 104. 21 (3 )°;β= 106. 91 (3) °;γ= 94. 94 (3 )°;V = 0. 6 235 (2 ) nm3;Z = 2. The complex 2 crystallized in the triclinic space P-l with o=0. 75833(15) n…查看全部>>
檀鑫;周荫庄
首都师范大学化学系,北京100048首都师范大学化学系,北京100048
化学化工
微波合成超分子配合物晶体结构
microwave synthesissupramolecular complexescrystal structure
《首都师范大学学报（自然科学版）》 2011 (6)
37-41,47,6
北京市教育委员会科技发晨计划面上项目(No.KM200910028011)
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