色谱2011，Vol.29Issue(12)：1160-1164,5.DOI:10.3724/SP.J.1123.2011.01160
固相萃取-高效液相色谱-质谱法测定海水中的烷基酚和烷基酚聚氧乙烯醚
Determination of alkylphenol and alkylphenolpolyethoxylates in brine by solid phase extraction and high performance liquid chromatography-mass spectrometry
摘要
Abstract
A simple method based on solid phase extraction ( SPE) coupled with high performance liquid chromatography-mass spectrometry (HPLC-MS) was developed for the determination of octylphenol (OP) , nonylphenol (NP) , octylphenol ethoxylates (OPEOs) and nonylphe-nol ethoxylates ( NPEOs) in brine. The extraction and cleanup of brine samples were performed on C18 solid-phase extraction cartridges. The complete separation among OP, NP, OPEOs and NPEOs was achieved on a Hypersil GOLD analytical column with methanol-water as the mobile phase. The determination was achieved using HPLC-MS with electrospray ionization (ESI) in selected ion monitoring mode. The results showed that the average recoveries of target compounds were 59.6% - 104.4% and the corresponding relative standard deviations (RSDs, n = 3) were 1. 0% - 13. 5%. The instrumental limits of detection for the compounds were 0. 08 - 3 μg/L. This method was applied to the analysis of the samples of seawater near Dalian coast. The results showed that both NP and NPEOs were detected in all samples and their concentrations in seaport and oil port were much higher than those in other sampling sites.关键词
回相萃取/高效液相色谱-质谱/烷基酚/烷基酚聚氧乙烯醚/海水Key words
solid phase extraction (SPE)/ high performance liquid chromatography-mass spectrometry {HPLC-MS)/ alkylphenol/ alkylphenolpolyethoxylate/ brine分类
化学化工引用本文复制引用
王金成,熊力,张海军,陈吉平..固相萃取-高效液相色谱-质谱法测定海水中的烷基酚和烷基酚聚氧乙烯醚[J].色谱,2011,29(12):1160-1164,5.基金项目
科技部重大专项课题(No.2009ZX07527-001) （No.2009ZX07527-001）
