石油化工2011，Vol.40Issue(11)：1258-1262,5.
碳酸二甲酯法合成聚碳酸酯及其步缩聚反应研究进展
Research Progresses in Synthesis of Polycarbonate from Dimethyl Carbonate and the Polycondensation
摘要
Abstract
Research progresses in synthesis of polycarbonate (PC) from dimethyl carbonate (DMC) were introduced. Selective synthesis of the intermediate two-methylcarbonate-ended-bisphenol A (DmC( 1)) from DMC were discussed. It was found that preparation of the suitable catalysts was the main way for increase of the selectivity and yield of DmC (1). The effects of the texture and surface properties of the catalysts on the carboxymethylation and methylation of bisphenol A with DMC were discussed. It was put forward that loading of organo tin oxides on the mesoporous support could promote DmC( 1) synthesis. The main influence factors for PC synthesis from DMC were investigated and the polycondensation process was analyzed. The foreground and the existent problems for PC synthesis from DMC were reviewed.关键词
碳酸二甲酯/聚碳酸酯/双酚A/二甲氧基碳酸双酚A二酯/有机氧化锡/缩聚反应/缩聚催化剂Key words
dimethyl carbonate/ polycarbonate/ bisphenol A/ two-methylcarbonate-ended-bisphenol A/organo tin oxide/ polycondensation/ polycondensation catalyst分类
化学化工引用本文复制引用
明军,李振环,程博闻,苏坤梅,郝婷..碳酸二甲酯法合成聚碳酸酯及其步缩聚反应研究进展[J].石油化工,2011,40(11):1258-1262,5.基金项目
国家自然科学基金项目(2100607 1/B0607,30900092/C020303) （2100607 1/B0607,30900092/C020303）
天津市自然科学基金项目(09JCYBJC03000). （09JCYBJC03000）
