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浆态床醇醚燃料合成技术及反应器数学模型

应卫勇 陈振 张海涛 房鼎业

石油化工2011,Vol.40Issue(12):1267-1274,8.
石油化工2011,Vol.40Issue(12):1267-1274,8.

浆态床醇醚燃料合成技术及反应器数学模型

Direct Synthesis Process for Alcohol/Ether Fuel in Bubble Column Slurry Reactor and Mathematical Models

应卫勇 1陈振 1张海涛 1房鼎业1

作者信息

  • 1. 华东理工大学化学工程联合国家重点实验室大型工业反应器工程教育部工程研究中心,上海200237
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摘要

Abstract

Dimethyl ether is used as an ideal civil and vehicle' s clean fuel. Alcohol/ether synthesis in bubble column slurry reactor has become a hot spot for the research in the world. The progresses in the research for the catalysts, the reaction kinetics, the bubble characteristics, the gas-liquid mass transfer coefficient and the mathematical reactor model for the bubble column slurry reactor were reviewed. In research and development situation at present, direct synthesis process for the alcohol/ ether fuel in the bubble column slurry reactor is the future development orientation for dimethyl ether production technologies. The present urgent problems to be solved mainly focused on the development of the distinctive commercial catalysts matching with the liquid, the separation of solid and liquid and the catalyst regeneration.

关键词

合成气/二甲醚/醇醚燃料/浆态床反应器/反应动力学/气泡特征/气液传质

Key words

syngas/ dimethyl ether/ alcohol/ether fuel/ bubble column slurry reactor/ reaction kinetics/ bubble characteristic/ gas-liquid mass transfer

分类

化学化工

引用本文复制引用

应卫勇,陈振,张海涛,房鼎业..浆态床醇醚燃料合成技术及反应器数学模型[J].石油化工,2011,40(12):1267-1274,8.

基金项目

国家重点基础研究发展规划项目(2005 CB21205) (2005 CB21205)

国家科技支撑计划项目(2006BAE02B02). (2006BAE02B02)

石油化工

OA北大核心CSCDCSTPCD

1000-8144

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