石油化工2011，Vol.40Issue(12)：1321-1324,4.
新型双苯并咪唑润滑油添加剂的合成及其多效性能研究
Synthesis and Multiple-Effect of Bis-Benzimidazole as Lubricant Additive
摘要
Abstract
A new lubricant additive 1,3-bis( 1-tertiary buty1-2-benzimidazy1)-2-thiopropane (tBu-BIMS) was synthesized from o-phenylenediamine, tert-buty1 bromine and 2,2'-thiodiacetic acid. The structure of the product was characterized by means of MS, FTIR and 'H NMR. The corrosion inhibition effect for Q235 steel and the antiwear and antifriction properties of the lubricant additive were evaluated by corrosion test and four-ball test in rapeseed oil. The results showed that tBu-BIMS had good corrosion inhibition effect for Q235 steel in petroleum ether with sulfur of 0. 2 mg/g. When the concentration of the tBu-BIMS was 5 × 10 -5 mol/L, the corrosion inhibition efficiency could reach more than 90%. The lubricant additive could evidently reduce the friction coefficient of rapeseed oil and the wear scar diameters of steel ball. When the mass fraction of tBu-BIMS was 0. 75% , the wear scar diameters could be reduced by 30. 88% .关键词
1,3 -二(1-叔丁基-2-苯并咪唑)-2-硫代丙烷/润滑油添加剂/缓蚀性能/抗磨减摩性能Key words
1, 3-bis ( 1-tertiary butyl-2-benzimidazy1)-2-thiopropane/ lubricant additive/ anticorrosion / antiwear and antifriction分类
化学化工引用本文复制引用
钱建华,张月,郑艳秋,刘琳..新型双苯并咪唑润滑油添加剂的合成及其多效性能研究[J].石油化工,2011,40(12):1321-1324,4.基金项目
辽宁'百千万人才工程'培养经费资助(2008921042) （2008921042）
辽宁省优秀人才支持计划资助项目(2009 R02). （2009 R02）
